Title

SYNTHESIS AND CHARACTERIZATION OF NANOCOMPOSITES COATING BASED ON INORGANIC OCTAHEDRAL CLUSTER UNITS FABRICATED BY ELECTROPHORETIC DEPOSITION PROCESS

Conference Dates

October 1-6, 2017

Abstract

Composite nanoarchitectures represent a new class of nanostructured entities that integrate various dissimilar nanoscale building blocks including clusters, particles, wires and films [1]. The heterogeneous composite nanostructured materials are composed by definition of multi-(nano)components, each tailored to address different requirements. As one of the nanocomponents, nanometer sized transition metal clusters (<2 nm), which consist of less than a few dozens of metal atoms, could be defined as a link between atom and nanoparticle [2-7]. In this presentation, the first preparation of functional thin films based on octahedral molybdenum metal clusters deposited on ITO glass substrate by EPD will be discussed in detail [8]. More generally, we will focus on our recent results on thin films for optical and energy applications [9-10].

References

[1] R. Liu et al., Chem. Commun., 2011, 47, 1384

[2] F. A. Cotton, Inorg. Chem., 1964, 3, 1217

[3] A. Perrin et al., C. R. Chimie, 2012, 15, 815

[4] Y. Luab et al., Chem. Soc. Rev., 2012, 41, 3594

[5] V. Fedorov, J. Clust. Sci., 2015, 26, 3

[6] S. Cordier et al., J. Inorg. Organomet. Polym., 2015, 25 189

[7] F. Grasset et al., Adv. Mater., 2008, 20, 1710

[8] T.K.N Nguyen et al., ECS J. Solid State Sci. Technol., 2016, (10) R178-R186

[9] T. G. Truong et al., Sci. Technol. Adv. Mat., 2016, 17(1), 443

[10] A. Renaud et al., ChemistrySelect, 2016, 1, 2284

Additional Files
6 - Fabien Grasset.pdf (86 kB)

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