Synthesis of geopolymer foams for decontamination of liquid nuclear waste
May 27-June 1, 2018
Liquid radioactive waste is produced in the nuclear industry and has to be treated to firstly minimize their impact on environment and secondly to propose an ultimate confinement matrix. One way to decontaminate these waste is to synthesize inorganic monolithic filters that are less sensitive to radiolysis phenomena than organic ones. Geopolymer cements are good candidates to fulfill these specifications since intrinsically they are mesoporous with high specific surface area  and compatible with specific grafting agents which allow to trap selectively radionucleides of interest (especially the cesium) . For this purpose, a monolithic geopolymer with good mechanical resistance and hierarchical porous network (tailored open macroporosity) was synthesized.
From this geopolymer foam, the precipitation of copper hexacyanoferrate into the porous network has been performed in order to trap selectively the cesium. The functionalized foams were characterized and the trapping capacity of Cs was assessed. After having determined the sorption kinetics, sorption isotherms were performed and the maximum sorption capacity, Q = 120 mg/g, was measured. Tests in a radioactive environment were also carried out in order to validate the performance of the material in real conditions (traces of Cs in fresh water). The results show that the functionalized material is capable of selectively trapping Cs with a distribution coefficient Kd of 2.37 105 ml/g. The results demonstrate remarkable potential of this innovative material for Cs removal from liquid nuclear waste.
 Steins, P., A. Poulesquen, O. Diat, and F. Frizon, Structural Evolution during Geopolymerization from an Early Age to Consolidated Material. Langmuir, 2012. 28(22): p. 8502-8510.
 Poulesquen. A, A. Gerenton, D. Lambertin, T. Piallat, F. Frizon, Y. Barré, A. Grandjean, Procédé de préparation d’une mousse de géopolymère fonctionnalisée, ladite mousse fonctionnalisée et ses utilisations », Brevet, FR 15/53868
Svetlana Petlitckaia, Yves Barré, and Arnaud Poulesquen, "Synthesis of geopolymer foams for decontamination of liquid nuclear waste" in "International Conference on Alkali Activated Materials and Geopolymers: Versatile Materials Offering High Performance and Low Emissions", J. Provis, University of Sheffield C. Leonelli, Univ. of Modena and Reggio Emilia W. Kriven, Univ. of Illinois at Urbana-Champaign A. Boccaccini, Univ. of Erlangen-Nuremberg A. Van Riessen, Curtin University, Australia Eds, ECI Symposium Series, (2018). http://dc.engconfintl.org/geopolymers/68