RE2O3 dissolution kinetics and mechanisms in CAS silicate melt: Influence of the rare earth
June 24-29, 2018
Fine particles of sand, dust or volcanic ashes ingested by aircraft engines are well-known to damage 8YPSZ Thermal Barrier Coating (TBC). In service, these particles deposit on hot TBC surface (≥ 1200°C) as molten silicate and infiltrate coating porous microstructure. They are mainly constituted of CaO-MgO-Al2O3-SiO2 (CMAS) in variable proportions and also contain metallic oxides. Gd2Zr2O7 TBC has shown efficiency to mitigate synthetic CMAS infiltration due to its reactivity with CMAS . Indeed, the dissolution reaction leads to rapid formation of a sealing-layer in the topcoat mainly constituted of crystalline Ca2Gd8(SiO4)6O2 apatite. However, this phase is not always stable in contact with CMAS and many rare-earth silicates may compete with apatite crystallization . Several rare-earth oxides RE2O3 can be considered to replace yttria in ZrO2-based TBC but little is known on reaction kinetics and thermodynamics involving RE2O3 and multi-component CMAS system.
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François Perrudin, M-H. Vidal-Sétif, C. Rio, C. Petitjean, P-J. Panteix, and M. Vilasi, "RE2O3 dissolution kinetics and mechanisms in CAS silicate melt: Influence of the rare earth" in "Thermal Barrier Coatings V", Prof. Dr. Robert Vaßen, Forschungszentrum Jülich GmbH, Germany Brian Hazel, Pratt & Whitney, USA Prof. Dr. Uwe Schulz, German Aerospace Center, Germany Dr. Michael J. Maloney, Pratt & Whitney, USA Dr. Ram Darolia, GE Aviation (Retired), USA Eds, ECI Symposium Series, (2018). https://dc.engconfintl.org/tbcv/18